Title : Sensing mechanism elucidation and performance optimization of perovskite-based gas sensors for ammonia gas detection
Abstract:
Understanding the sensing mechanism is crucial for optimizing perovskite-based sensors, such as MAPbI3. Despite stability challenges, our study reveals a consistent increase in current during varying concentrations of ammonia. The interaction involves the reduction of MA+ to MA and the oxidation of NH3 into NH4+, forming a cation exchange mechanism. This process enhances carrier concentration, boosting electrical conductivity. The smaller ionic radius of NH4+ facilitates effective cation exchange, while the electron lone pair of the nitrogen atom in alkylamine molecules permeates the perovskite structure, leading to improved conductivity. Our study addresses gaps in understanding perovskite-based gas sensors, providing insights into the complex sensing mechanism of MAPbI3 during ammonia detection.